Match the entries from Column $I$ and Column $II$ and choose the correct order.
$A$. Leclanche cell$1$. Converts energy of combustion into electrical energy
$B$. Fuel cell$2$. Rechargeable cell
$C$. Ni-Cd cell$3$. At anode,$Zn \longrightarrow Zn^{2+} + 2e^{-}$

  • A
    $A-3, B-1, C-2$
  • B
    $A-1, B-2, C-3$
  • C
    $A-3, B-2, C-1$
  • D
    $A-2, B-1, C-3$

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Impure copper containing $Fe$,$Au$,and $Ag$ as impurities is electrolytically refined. $A$ current of $140 \ A$ for $482.5 \ s$ decreased the mass of the anode by $22.26 \ g$ and increased the mass of the cathode by $22.011 \ g$. The percentage of iron in the impure copper is (Given molar mass $Fe = 55.5 \ g \ mol^{-1}$,molar mass $Cu = 63.54 \ g \ mol^{-1}$)

The molar conductivity of acetic acid solution at infinite dilution is $390 \ S \ cm^2 \ mol^{-1}$. What is the molar conductivity of $0.01 \ M$ acetic acid solution (in $S \ cm^2 \ mol^{-1}$)? (Given: $K_{a}(CH_3COOH) = 1.8 \times 10^{-5}$,assume $1-\alpha \approx 1$)

Based on the following information,arrange four metals,$A$,$B$,$C$,and $D$,in order of increasing ability to act as reducing agents:
$(I)$ Only $C$ reacts with $1 \ M \ HCl$ to give $H_{2(g)}$.
$(II)$ When $A$ is added to a solution of the other metal salts,metallic $D$ is formed,but not $B$ or $C$.

The process of rusting of iron occurs as follows:
$Fe \rightarrow Fe^{2+} + 2e^{-}, E^{o} = 0.44 \ V$
$2H^{+} + 2e^{-} + \frac{1}{2} O_2 \rightarrow H_2O_{(l)}, E^{o} = 1.23 \ V$
Then for this reaction,$\Delta G^{o} = .... \ kJ/mol$

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The number of incorrect statements from the following is:
$A.$ The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy.
$B.$ $E_{cell}^0$ is dependent on the pressure.
$C.$ $\frac{dE_{cell}^0}{dT} = \frac{\Delta_{r}S^0}{nF}$.
$D.$ $A$ cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference.

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