Molal depression constant $(K_{f})$ is dependent on

$45 \ g$ of ethylene glycol $(C_{2}H_{6}O_{2})$ is mixed with $600 \ g$ of water. Calculate $(a)$ the freezing point depression and $(b)$ the freezing point of the solution.

....... $g$ will be the amount of ice separated on cooling a solution of $40 \ g$ ethylene glycol in $400 \ g$ water up to $-9.3 \ ^oC$. ($K_f$ for water is $1.86 \ K \ kg \ mol^{-1}$)

The freezing point of a diluted milk sample is found to be $-0.2\ ^\circ C$,while it should be $-0.5\ ^\circ C$ for pure milk. How much water has been added to pure milk to make the diluted sample?

$1.95 \ g$ of non-volatile and non-electrolyte solute dissolved in $100 \ g$ of benzene lowered the freezing point of it by $0.64 \ K$. The molar mass of the solute (in $g \ mol^{-1}$) is: $(K_{f}(C_6H_6) = 5.12 \ K \ kg \ mol^{-1})$

If an aqueous solution of glucose is allowed to freeze,then crystals of which substance will be separated out first?