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Explain the electrolytic refining of metals.

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Match the refining methods (Column $I$) with metals (Column $II$).
Column $I$ (Refining methods) Column $II$ (Metals)
$(I)$ Liquation $(a)$ $Zr$
$(II)$ Zone refining $(b)$ $Ni$
$(III)$ Mond process $(c)$ $Sn$
$(IV)$ Van Arkel Method $(d)$ $Ga$

The zone refining method is used for the purification of .....

Which element is obtained in the pure form by the Van Arkel method?

Which method is used for refining $Zr$ and $Ti$? Explain with equations.

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