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Which is correctly matched?

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The exact order of acidity of the compounds $p-$nitrophenol, acetic acid, acetylene and ethanol is

The least acidic compound among the following is:

The correctly matched pairs of the following are given by the sets $:$
$(A)$ Neopentane $-$ position isomer of isopentane
$(B)$ Isopentane $-$ three primary carbon atoms
$(C)$ Isobutylene $-$ no secondary carbon
$(D)$ Isobutane $-$ two primary carbons

The degree of unsaturation (also known as double bond equivalent or index of hydrogen deficiency) for a compound with the molecular formula $C_{20}H_{22}O_2$ is:

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