Obtain the equation for $\gamma = \frac{C_P}{C_V}$ in terms of the degree of freedom $f$.

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(D) For a gas with $f$ degrees of freedom,the internal energy $U$ of $1 \text{ mole}$ of gas is given by:
$U = f \times \frac{1}{2} k_B T \times N_A = \frac{1}{2} f RT$ (since $k_B N_A = R$).
From the definition of molar specific heat at constant volume:
$C_V = \frac{dU}{dT} = \frac{d}{dT} \left( \frac{1}{2} f RT \right) = \frac{1}{2} f R$.
Using Mayer's relation for molar specific heat at constant pressure:
$C_P = C_V + R = \frac{1}{2} f R + R = \left( \frac{f}{2} + 1 \right) R$.
The adiabatic index $\gamma$ is defined as the ratio of specific heats:
$\gamma = \frac{C_P}{C_V} = \frac{(\frac{f}{2} + 1) R}{\frac{1}{2} f R}$.
Simplifying the expression:
$\gamma = \frac{f + 2}{f} = 1 + \frac{2}{f}$.

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Let $\gamma_1$ be the ratio of molar specific heat at constant pressure and molar specific heat at constant volume of a mono-atomic gas and $\gamma_2$ be the similar ratio of a diatomic gas. Considering the diatomic gas molecule as a rigid rotator, the ratio $\gamma_1/\gamma_2$ is

Column-$I$ represents the type of gas and Column-$II$ represents the ${C_P}$ value for that type of gas. Match them correctly:
Column-$I$Column-$II$
$(a)$ Monoatomic gas$(i)$ ${C_P} = \frac{3}{2}R$
$(b)$ Diatomic gas with vibration$(ii)$ ${C_P} = \frac{5}{2}R$
$(iii)$ ${C_P} = \frac{7}{2}R$
$(iv)$ ${C_P} = \frac{9}{2}R$

The specific heat of a gas:

Specific heats of an ideal gas at constant pressure and volume are denoted by $C_p$ and $C_v$ respectively. If $\gamma = \frac{C_p}{C_v}$ and $R$ is the universal gas constant,then $C_v$ is equal to:

The ratio of the specific heats $\frac{C_p}{C_v} = \gamma$ in terms of degrees of freedom $(n)$ is given by

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