Of the following complexes,the one with the largest value of crystal field splitting energy is

  • A
    $[Fe(H_2O)_6]^{3+}$
  • B
    $[Ru(CN)_6]^{3-}$
  • C
    $[Fe(H_2O)_6]^{2+}$
  • D
    $[Fe(NH_3)_6]^{3+}$

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What is the correct order of increasing field strength for the ligands $NH_3$,$en$,$CN^-$,and $CO$?

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Simplified absorption spectra of three complexes $(i), (ii)$ and $(iii)$ of $M^{n+}$ ion are provided below; their $\lambda_{max}$ values are marked as $A, B$ and $C$ respectively. The correct match between the complexes and their $\lambda_{max}$ values is
$(i)$ $[M(NCS)_6]^{(-6+n)}$
$(ii)$ $[MF_6]^{(-6+n)}$
$(iii)$ $[M(NH_3)_6]^{n+}$

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