On adding $0.1 \ M$ solution each of $[Ag^+]$,$[Ba^{2+}]$,and $[Ca^{2+}]$ to a $Na_2SO_4$ solution,which species precipitates first? Given: $K_{sp}(BaSO_4) = 10^{-11}$,$K_{sp}(CaSO_4) = 10^{-6}$,$K_{sp}(Ag_2SO_4) = 10^{-5}$.

  • A
    $Ag_2SO_4$
  • B
    $BaSO_4$
  • C
    $CaSO_4$
  • D
    All of these

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