On reaction with $Cl_2$,phosphorus forms two types of halides $A$ and $B$. Halide $A$ is a yellowish-white powder,while halide $B$ is a colourless oily liquid. Identify $A$ and $B$ and write the formulas of their hydrolysis products.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) is $PCl_5$ and $B$ is $PCl_3$.
$B (PCl_3)$ undergoes hydrolysis to form phosphorous acid $(H_3PO_3)$ and hydrogen chloride $(HCl)$:
$PCl_3 + 3 H_2O \rightarrow H_3PO_3 + 3 HCl$
$A (PCl_5)$ undergoes hydrolysis to form phosphoric acid $(H_3PO_4)$ and hydrogen chloride $(HCl)$:
$PCl_5 + 4 H_2O \rightarrow H_3PO_4 + 5 HCl$

Explore More

Similar Questions

Which of the following oxyacids is the strongest acid?

Which of the following compounds releases nitrogen dioxide $(NO_2)$ upon heating?

The bond energies (in $kJ \ mol^{-1}$) of $P-H$, $As-H$, and $N-H$ are respectively:

The oxidation state of phosphorus in cyclo-tri-meta phosphoric acid is

In the reaction $4HNO_3 + P_4O_{10} \to 4HPO_3 + x$,the product $x$ is

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo