On saturating an aqueous solution of $Cu(II)$,$Pb(II)$,and $Zn(II)$ ions with $H_2S$,which of the following will precipitate?

  • A
    Only $CuS$
  • B
    Only $PbS$
  • C
    Both $CuS$ and $PbS$
  • D
    $CuS$,$PbS$,and $ZnS$

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$(A)$ $CuSO_4$ (acidified with acetic acid) $+$ $K_4[Fe(CN)_6]$ $\rightarrow$ Chocolate brown precipitate.
$(B)$ $FeCl_3 + K_4[Fe(CN)_6]$ $\rightarrow$ Prussian blue precipitate.
$(C)$ $ZnCl_2 + K_4[Fe(CN)_6]$,neutralised with $NH_4OH$ $\rightarrow$ White or bluish white precipitate.
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$(E)$ $BaCl_2 + K_4[Fe(CN)_6]$,neutralised with $NaOH$ $\rightarrow$ White precipitate.
Choose the correct answer from the options given below:

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