One mole of an ideal gas is allowed to expand freely and adiabatically into vacuum until its volume has doubled. Which of the following statements is $NOT$ true concerning this expansion?

For the reaction $2X_{(s)} + 2Y_{(s)} \to 2C_{(\ell)} + D_{(g)}$,the value of $q_p$ is $-28 \, \text{kcal mol}^{-1}$ at $2700 \, ^\circ\text{C}$. Calculate the value of $q_v$ in $\text{kcal mol}^{-1}$.

$A$ gas (Molar mass $= 280 \ g \ mol^{-1}$) was burnt in excess $O_2$ in a constant volume calorimeter and during combustion the temperature of calorimeter increased from $298.0 \ K$ to $298.45 \ K$. If the heat capacity of calorimeter is $2.5 \ kJ \ K^{-1}$ and enthalpy of combustion of gas is $9 \ kJ \ mol^{-1}$,then the amount of gas burnt is $...... \ g$. (Nearest Integer)

For an ideal gas, consider only $P-V$ work in going from an initial state $X$ to the final state $Z$. The final state $Z$ can be reached by either of the two paths shown in the figure. Which of the following choice$(s)$ is (are) correct? [take $\Delta S$ as change in entropy and $w$ as work done].
$(A)$ $\Delta S_{X \to Z} = \Delta S_{X \to Y} + \Delta S_{Y \to Z}$
$(B)$ $w_{X \to Z} = w_{X \to Y} + w_{Y \to Z}$
$(C)$ $w_{X \to Y \to Z} = w_{X \to Y} + w_{Y \to Z}$
$(D)$ $\Delta S_{X \to Y \to Z} = \Delta S_{X \to Y}$

The enthalpy of neutralisation of $KOH$ by a weak acid $(HA)$ is $-12.2 \ kcal \ mol^{-1}$. If the weak acid is $10 \%$ ionised,then the enthalpy of dissociation of $1 \ mole$ of $HA$ is. Given that the enthalpy of neutralisation of $KOH$ by $HCl$ is $-13.7 \ kcal \ mol^{-1}$.

For the reactions,$C + O_2 \to CO_2; \Delta H = -393 \ J$
$2Zn + O_2 \to 2ZnO; \Delta H = -412 \ J$