(B) In $o-$nitrophenol,the $-OH$ group forms an intramolecular hydrogen bond with the adjacent nitro group. This makes the $-OH$ group unavailable for

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$o-$Nitrophenol shows intramolecular $H-$bonding.

(B) In $o-$nitrophenol,the $-OH$ group forms an intramolecular hydrogen bond with the adjacent nitro group. This makes the $-OH$ group unavailable for intermolecular hydrogen bonding with water molecules. Consequently,$o-$nitrophenol exhibits lower solubility in water compared to $m-$ and $p-$nitrophenols,which form intermolecular hydrogen bonds with water.

Class 11 Chemistry Chemical Bonding and Molecular Structure Hydrogen bonding

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$o-$Nitrophenol is less soluble in water than $p-$ and $m-$nitrophenols because:

AIIMS 2019 All AIIMS

A
$o-$Nitrophenol is more volatile than $m-$ and $p-$ isomers.
B
$o-$Nitrophenol shows intramolecular $H-$bonding.
C
$o-$Nitrophenol shows intermolecular $H-$bonding.
D
Melting point of $o-$nitrophenol is lower than those of $m-$ and $p-$ isomers.

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Chemical Bonding and Molecular Structure

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Hydrogen bonding

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The boiling point of $CH_3OH$ (methanol) is greater than that of $CH_3SH$ (methyl thiol) because

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Would you expect the hydrides of $N$,$O$ and $F$ to have lower boiling points than the hydrides of their subsequent group members? Give reasons.

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Explain why,in spite of having nearly the same electronegativity,oxygen forms hydrogen bonding while chlorine does not.

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The bond angle between $H-O-H$ in ice is closest to

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The steam volatile compounds among the following are $:$
$(A)$ $o$-nitrophenol
$(B)$ $o$-nitroaniline
$(C)$ $p$-aminophenol
$(D)$ $p$-hydroquinone
Choose the correct answer from the options given below $:$

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$o-$Nitrophenol is less soluble in water than $p-$ and $m-$nitrophenols because:

Similar Questions

The boiling point of $CH_3OH$ (methanol) is greater than that of $CH_3SH$ (methyl thiol) because

Would you expect the hydrides of $N$,$O$ and $F$ to have lower boiling points than the hydrides of their subsequent group members? Give reasons.

Explain why,in spite of having nearly the same electronegativity,oxygen forms hydrogen bonding while chlorine does not.

The bond angle between $H-O-H$ in ice is closest to

The steam volatile compounds among the following are $:$ $(A)$ $o$-nitrophenol $(B)$ $o$-nitroaniline $(C)$ $p$-aminophenol $(D)$ $p$-hydroquinone Choose the correct answer from the options given below $:$

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The steam volatile compounds among the following are $:$
$(A)$ $o$-nitrophenol
$(B)$ $o$-nitroaniline
$(C)$ $p$-aminophenol
$(D)$ $p$-hydroquinone
Choose the correct answer from the options given below $:$