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What is glacial acetic acid?

What is the percentage of acetic acid present in vinegar?

Assertion : $\beta$-Keto carboxylic acids lose $CO_2$ when heated at about $370 \ K$.
Reason : An enol is first formed by loss of $CO_2$,but it readily tautomerises to the more stable ketone.

In the given reaction :
$CH_3-COOH$ $\mathop{\xrightarrow{(i) Br_2/P}}_{(ii) NaCN, (iii) H_2O/H^{+}/\Delta}$ $[X]$
$[X]$ will be :

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Which of the following acids has the lowest $pK_a$ value?

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