Select the correct statement.

  • A
    Acidic strength of $HBr > HCl$,but the reverse is true for their reducing property.
  • B
    Basic strength of $PH_3 > AsH_3$,but the reverse is true for their bond angle.
  • C
    Dipole moment of $CH_3Cl > CH_3F$,but the reverse is true for their $H-C-H$ bond angle.
  • D
    $Ka_1$ of fumaric acid is higher than maleic acid,but the reverse is true for their $Ka_2$.

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An aqueous solution of a non-volatile solute boils at $100.15\,^{\circ}C$. If the solution is diluted with an equal volume of water,the freezing point of the resulting solution will be ...... $^{\circ}C$. (Given: $K_b = 0.512\,K\,kg\,mol^{-1}$ and $K_f = 1.86\,K\,kg\,mol^{-1}$ for water)

The $pH$ of a $0.1 \ M$ monobasic acid is $2$. Its osmotic pressure at a given temperature $T \ (K)$ is: (Given that the effective concentration for osmotic pressure is $(1+\alpha) \times$ concentration of acid, where $\alpha$ is the degree of dissociation)

The ionization constant of a monobasic acid $HA$ is to be determined. If a $0.025 \ m$ aqueous solution of the acid freezes at $-0.060 \ ^{\circ}C$,calculate the ionization constant $K_a$. (Assume molality = molarity and $K_f(H_2O) = 1.86 \ K \ kg \ mol^{-1}$).

$A$ solution of urea (molar mass $60 \, g \, mol^{-1}$) boils at $100.18 \, ^oC$ at atmospheric pressure. If $K_f$ and $K_b$ for water are $1.86$ and $0.512 \, K \, kg \, mol^{-1}$ respectively,the above solution will freeze at ........... $^oC$.

What type of solution is iodine in air?

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