Sodium phenoxide when heated with CO_2 under | vedclass

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Question

(A) The reaction of sodium phenoxide with $CO_2$ at $125\,^{\circ}C$ and $5 \ atm$ pressure is the Kolbe-Schmidt reaction,which yields salicylic acid

Vedclass · Accepted Answer

$2-$Acetoxybenzoic acid

Vedclass · Answer

(A) The reaction of sodium phenoxide with $CO_2$ at $125\,^{\circ}C$ and $5 \ atm$ pressure is the Kolbe-Schmidt reaction,which yields salicylic acid ($2$-hydroxybenzoic acid) as the intermediate $B$.In the second step,salicylic acid undergoes acetylation with acetic anhydride $(Ac_2O)$ to form acetylsalicylic acid,commonly known as Aspirin,which is the major product $C$.The structure of $C$ is $2$-acetoxybenzoic acid.

Sodium phenoxide when heated with $CO_2$ under pressure at $125\,^{\circ}C$ yields a product which on acetylation produces $C$. The major product $C$ would be

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