Statement-$I$: Most carboxylic acids exist as dimers in vapour phase or in aprotic solvents due to intermolecular hydrogen bonding.
Statement-$II$: Higher carboxylic acids are practically insoluble in water due to the increased hydrophobic interaction of the hydrocarbon part.

  • A
    Statement $I$ is correct and Statement $II$ is incorrect
  • B
    Statement $I$ is incorrect and Statement $II$ is correct
  • C
    Both Statement $I$ and Statement $II$ are correct
  • D
    Both Statement $I$ and Statement $II$ are incorrect

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The correct order of increasing acid strength of the compounds is:
$(A) CH_3CO_2H$
$(B) MeOCH_2CO_2H$
$(C) CF_3CO_2H$
$(D) (CH_3)_2CHCO_2H$

Identify product $B$ in the above reaction sequence.

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What will happen if $LiAlH_4$ is added to an ester?

When carboxylic acid reacts with organolithium reagents to give ketones,side reactions sometimes occur. For example,
$HOCH_2CH_2CH(CH_3)CH_2CH_2COOH$ $\xrightarrow[(x) \, CH_3Li]{tetrahydro\,furan}$ $\xrightarrow[NH_4Cl]{H_2O}$ $\underset{63\%}{\text{Compound } A: HOCH_2CH_2CH(CH_3)CH_2CH_2COCH_3}$ + $\underset{37\%}{\text{Compound } (B)}$
The value of $(x)$ in the above reaction is:

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Predict the product of hydrolysis of the above molecule.

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