The $V-C$ distance in $[V(CO)_6]$ and $[V(CO)_6]^-$ are respectively (in $pm$):

  • A
    $100, 200$
  • B
    $193, 200$
  • C
    $200, 193$
  • D
    $193, 193$

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Which is not true about metal carbonyls?

Wilkinson's catalyst,used as a homogeneous catalyst in the hydrogenation of alkenes,contains which of the following metals?

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$A$. Total number of valence shell electrons at metal centre in $Fe(CO)_5$ or $Ni(CO)_4$ is $16$
$B$. These are predominantly low spin in nature
$C$. Metal-carbon bond strengthens when the oxidation state of the metal is lowered
$D$. The carbonyl $C-O$ bond weakens when the oxidation state of the metal is increased

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