The $\Delta H$ for vaporisation of a liquid is $20 \, kJ/mol$. Assuming ideal behaviour,the change in internal energy for the vaporisation of $1 \, mole$ of the liquid at $60^{\circ} C$ and $1 \, bar$ is close to $.... \, kJ/mol$

  • A
    $13.2$
  • B
    $17.2$
  • C
    $19.5$
  • D
    $20.0$

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Enthalpy of formation of $CO_{2(g)}$,$H_2O_{(l)}$ and $C_6H_{12}O_{6(s)}$ are $-393$,$-286$ and $-1170 \ kJ \ mol^{-1}$ respectively. The quantity of heat liberated when $18 \ g$ of $C_6H_{12}O_{6(s)}$ is burnt completely in oxygen is (in $kJ$)

Calculate the difference between $\Delta H$ and $\Delta U$ for the following reaction at $25^{\circ} C$:
$C_2H_{6(g)} + 3.5O_{2(g)} \rightarrow 2CO_{2(g)} + 3H_2O_{(l)}$
(Given: $R = 8.314 \ J \ K^{-1} \ mol^{-1}$) (in $kJ$)

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The enthalpy of sublimation of $I_{2(s)}$ is $57.3 \, kJ \, mol^{-1}$ and the enthalpy of fusion is $15.5 \, kJ \, mol^{-1}$. The enthalpy of vaporization of $I_2$ is ..................... $kJ \, mol^{-1}$. (in $.8$)

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The entropy versus temperature plot for phases $\alpha$ and $\beta$ at $1 \ bar$ pressure is given. $S_T$ and $S_0$ are entropies of the phases at temperatures $T$ and $0 \ K$,respectively.
The transition temperature for $\alpha$ to $\beta$ phase change is $600 \ K$ and $C_{p, \beta} - C_{p, \alpha} = 1 \ J \ mol^{-1} \ K^{-1}$. Assume $(C_{p, \beta} - C_{p, \alpha})$ is independent of temperature in the range of $200$ to $700 \ K$. $C_{p, \alpha}$ and $C_{p, \beta}$ are heat capacities of $\alpha$ and $\beta$ phases,respectively.
$(1)$ The value of entropy change,$S_{\beta} - S_{\alpha}$ (in $J \ mol^{-1} \ K^{-1}$),at $300 \ K$ is. . . . . . .
$(2)$ The value of enthalpy change,$H_{\beta} - H_{\alpha}$ (in $J \ mol^{-1}$),at $300 \ K$ is.
[Use : $\ln 2 = 0.69$,Given : $S_{\beta} - S_{\alpha} = 0$ at $0 \ K$]

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