The $pH$ of a buffer solution decreases by $0.02$ units when $0.12 \ g$ of acetic acid is added to $250 \ mL$ of a buffer solution of acetic acid and potassium acetate at $27^{\circ} C$. The buffer capacity of the solution is

  • A
    $0.1$
  • B
    $10$
  • C
    $1$
  • D
    $0.4$

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One litre buffer solution was prepared by adding $0.10 \ mol$ each of $NH_3$ and $NH_4Cl$ in deionised water. The change in $pH$ on addition of $0.05 \ mol$ of $HCl$ to the above solution is $............ \times 10^{-2}$ ($Nearest$ $integer$) ($Given$: $pK_b$ of $NH_3 = 4.745$ and $\log_{10} 3 = 0.477$)

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