The average translational kinetic energy and the $r.m.s.$ speed of molecules in a sample of oxygen gas at $300 \, K$ are $6.21 \times 10^{-21} \, J$ and $484 \, m/s$ respectively. The corresponding values at $600 \, K$ are nearly (assuming ideal gas behaviour):

  • A
    $12.42 \times 10^{-21} \, J, \, 684 \, m/s$
  • B
    $8.78 \times 10^{-21} \, J, \, 684 \, m/s$
  • C
    $6.21 \times 10^{-21} \, J, \, 968 \, m/s$
  • D
    $12.42 \times 10^{-21} \, J, \, 968 \, m/s$

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$4.0 \, g$ of a gas occupies $22.4 \, L$ at $NTP$. The specific heat capacity of the gas at constant volume is $5.0 \, J K^{-1} mol^{-1}$. If the speed of sound in this gas at $NTP$ is $952 \, m s^{-1}$,then the heat capacity at constant pressure is .... $J K^{-1} mol^{-1}$ (Take gas constant $R = 8.3 \, J K^{-1} mol^{-1}$)

Initially,a gas of diatomic molecules is contained in a cylinder of volume $V_{1}$ at a pressure $P_{1}$ and temperature $250\, K$. Assuming that $25\%$ of the molecules get dissociated,causing a change in the number of moles. The pressure of the resulting gas at temperature $2000\, K$,when contained in a volume $2V_{1}$,is given by $P_{2}$. The ratio $\frac{P_{2}}{P_{1}}$ is:

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