The cell,$Zn\ |\ Zn^{2+} \,(1\ M)\ ||\ Cu^{2+}\ (1\ M)\ |\ Cu$ $(E^o_{cell} = 1.10\ V)$ was allowed to be completely discharged at $298\ K.$ The relative concentration of $Zn^{2+}$ to $Cu^{2+}$ $\left( \frac{[Zn^{2+}]}{[Cu^{2+}]} \right)$ is

  • A
    $9.65 \times 10^4$
  • B
    antilog $(24.08)$
  • C
    $37.3$
  • D
    $10^{37.3}$

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Calculate $E_{cell}$ for the following cell:
$Pt_{(s)} | H_{2(g)} | HA, 1 \ M \ (K_a = 10^{-7}) || HB, 1 \ M \ (K_a = 10^{-5}) | H_{2(g)} | Pt_{(s)}$ (in $V$)

In a cell reaction,a $2$ electron change occurs. The standard $e.m.f.$ of the cell at $25^\circ C$ is $0.295 \ V$. What is the equilibrium constant for the reaction at $25^\circ C$?

Considering the reaction $Cl_{2(g)} + 2Br^{-}_{(aq)} \rightarrow 2Cl^{-}_{(aq)} + Br_{2(l)}$,calculate the cell $emf$ in $V$ when $[Cl^{-}] = [Br_2] = [Br^{-}] = 0.01 \ M$ and $Cl_2$ gas is at $1 \ atm$ pressure. (Given $E^o = 0.29 \ V$ for the reaction)

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The half-cell reaction involving the quinhydrone electrode is shown below:
$HO-C_6H_4-OH_{(aq)} \rightleftharpoons O=C_6H_4=O_{(aq)} + 2H^+ + 2e^-$
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