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Which reaction is not named as a Friedel-Crafts reaction?

Which of the following is not used as an explosive?

The correct sequence of reagents used in the preparation of $4-$bromo$-2-$nitroethylbenzene from benzene is:

Assertion : $4-$Nitrochlorobenzene undergoes nucleophilic substitution more readily than chlorobenzene.
Reason : Chlorobenzene undergoes nucleophilic substitution by elimination-addition mechanism while $4-$nitrochlorobenzene undergoes nucleophilic substitution by addition-elimination mechanism.

$p-$Dichlorobenzene has a higher $m.p.$ than those of $o-$ and $m-$ isomers. Discuss.

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