The consecutive reaction $X$ $\longrightarrow Y$ $\longrightarrow Z$ takes place in a closed container. Initially,the container has $A_{0}$ moles of $X$ (and no $Y$ and $Z$). The plot of total moles of the constituents in the container as a function of time will be:

$A$ person's wound was exposed to some bacteria and then bacteria growth started to happen at the same place. The wound was later treated with some antibacterial medicine and the rate of bacterial decay $(r)$ was found to be proportional to the square of the existing number of bacteria at any instance. Which of the following set of graphs correctly represents the 'before' and 'after' situation of the application of the medicine?
[$Given: N = \text{No. of bacteria}, t = \text{time}$, bacterial growth follows $1^{st}$ order kinetics.]

The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two-step process shown below:
$O_{3(g)} + Cl_{(g)}^{\bullet} \to O_{2(g)} + ClO_{(g)}^{\bullet}$ ..... $(i)$ $K_i = 5.2 \times 10^9 \ L \ mol^{-1} \ s^{-1}$
$ClO_{(g)}^{\bullet} + O_{(g)}^{\bullet} \to O_{2(g)} + Cl_{(g)}^{\bullet}$ ..... $(ii)$ $K_{ii} = 2.6 \times 10^{10} \ L \ mol^{-1} \ s^{-1}$
The closest rate constant for the overall reaction
$O_{3(g)} + O_{(g)}^{\bullet} \to 2O_{2(g)}$ is ........... $L \ mol^{-1} \ s^{-1}$

For a first order reaction,which of the following statements is correct?

The given graph is a representation of kinetics of a reaction. The $y$ and $x$ axes for zero and first order reactions,respectively are

Under identical reaction conditions,the concentration of a substance is $1.386 \ mol \ m^{-3}$. It is halved in $40 \ s$ and $20 \ s$ by first-order and zero-order kinetics,respectively. The ratio of the rate constants for the first-order $(k_1)$ and zero-order $(k_0)$ reactions,$\left( \frac{k_1}{k_0} \right)$,is ............ $m^3 \ mol^{-1}$.