The correct order of the stoichiometries of A | vedclass

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(B) The reaction of coordination complexes with excess $AgNO_3$ precipitates the chloride ions present outside the coordination sphere (ionizable chlo

Vedclass · Accepted Answer

$3 \ AgCl, 2 \ AgCl, 1 \ AgCl$

Vedclass · Answer

(B) The reaction of coordination complexes with excess $AgNO_3$ precipitates the chloride ions present outside the coordination sphere (ionizable chlorides).$1$. $[Co(NH_3)_6]Cl_3$ contains $3$ ionizable $Cl^-$ ions,yielding $3 \ mol \ AgCl$.$2$. $[Co(NH_3)_5Cl]Cl_2$ contains $2$ ionizable $Cl^-$ ions,yielding $2 \ mol \ AgCl$.$3$. $[Co(NH_3)_4Cl_2]Cl$ contains $1$ ionizable $Cl^-$ ion,yielding $1 \ mol \ AgCl$.Thus,the correct order is $3 \ AgCl, 2 \ AgCl, 1 \ AgCl$.

The correct order of the stoichiometries of $AgCl$ formed when $AgNO_3$ in excess is treated with the complexes $CoCl_3 \cdot 6NH_3$,$CoCl_3 \cdot 5NH_3$,and $CoCl_3 \cdot 4NH_3$ respectively is:

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