The decomposition of $N_2O_5$ is a first order reaction represented by $N_2O_5 \to N_2O_4 + \frac{1}{2} O_2$. After $15 \ min$,the volume of $O_2$ produced is $9 \ mL$ and at the end of the reaction,it is $35 \ mL$. The rate constant is equal to:

  • A
    $\frac{1}{15} \ln \frac{35}{44}$
  • B
    $\frac{1}{15} \ln \frac{44}{26}$
  • C
    $\frac{1}{15} \ln \frac{44}{35}$
  • D
    $\frac{1}{15} \ln \frac{35}{26}$

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Calculate the time in seconds required to reduce the concentration of reactant to half of initial concentration for a first order reaction if the rate constant is $1.386 \times 10^{-3} \ s^{-1}$. (in $s$)

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