The electron affinities of halogens are $F = 322$,$Cl = 349$,$Br = 324$,$I = 295 \ kJ \ mol^{-1}$. The higher value for $Cl$ as compared to that of $F$ is due to

  • A
    Weaker electron-electron repulsion in $Cl$
  • B
    Higher atomic radius of $F$
  • C
    Smaller electronegativity of $F$
  • D
    More vacant $p-$subshell in $Cl$

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Among the following configurations,the element which has the highest electron affinity is

Consider the following conversions:
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$(iii) \, Cl_{(g)} + e^- \to Cl_{(g)}^{-}, \Delta H_3$
$(iv) \, O_{(g)}^{-} + e^- \to O_{(g)}^{2-}, \Delta H_4$
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Identify the element having positive electron gain enthalpy.

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