The $emf$ of a $Daniel$ cell at $298 \ K$ is ${E_1}$ for the cell reaction $Zn|ZnSO_4(0.01 \ M)||CuSO_4(1.0 \ M)|Cu$. When the concentration of $ZnSO_4$ is $1.0 \ M$ and that of $CuSO_4$ is $0.01 \ M$,the $emf$ changes to ${E_2}$. What is the relationship between ${E_1}$ and ${E_2}$?

  • A
    ${E_2} = 0 \neq {E_1}$
  • B
    ${E_1} > {E_2}$
  • C
    ${E_1} < {E_2}$
  • D
    ${E_1} = {E_2}$

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