The equilibrium concentrations of the species in the reaction $A + B \rightleftharpoons C + D$ are $2, 3, 10$ and $6 \, mol \, L^{-1}$,respectively at $300 \, K$. $\Delta G^{\circ}$ for the reaction is $(R = 2 \, cal \, mol^{-1} \, K^{-1})$ (in $, cal$)

  • A
    $-13.73$
  • B
    $1372.60$
  • C
    $-137.26$
  • D
    $-1381.80$

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The standard free energy change $(\Delta G^{\circ})$ for $50\%$ dissociation of $N_2O_4$ into $NO_2$ at $27^{\circ}C$ and $1\,atm$ pressure is $-x\,J\,mol^{-1}$. The value of $x$ is $......$ (Nearest Integer)
[Given: $R = 8.31\,J\,K^{-1}\,mol^{-1}$,$\log 1.33 = 0.1239$,$\ln 10 = 2.3$]

Hydrolysis of sucrose gives,
$Sucrose + H_{2}O \rightleftharpoons Glucose + Fructose$
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Solid $KClO_4$ is taken in a container maintained at a constant pressure of $1 \, atm$. Upon heating,the following equilibrium is obtained:
$2KClO_{4(s)} \rightleftharpoons 2KCl_{(s)} + 3O_{2(g)}$
If $\Delta H^o = 25 \, kcal/mol$ and $\Delta S^o = 50 \, cal/K \cdot mol$,at what temperature will equilibrium be established in the container (in $, K$)? (Ignore variation of $\Delta H^o$ and $\Delta S^o$ with temperature.)

The equilibrium constant $(K)$ of a reaction may be written as :

The correct relationship between standard free energy change $(\Delta G^o)$ and equilibrium constant $(K)$ is:

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