The following bimolecular elimination reaction $(E_2)$ is carried out with different halogen leaving groups. The per cent yield of the two products ($2$-hexene and $1$-hexene) for each leaving group is listed below.
Leaving groupConj. Acid $pK_a$$\%$-yield of $2$-hexene$\%$-yield of $1$-hexene
$X = I$$-10$$81\%$$19\%$
$X = Br$$-9$$72\%$$28\%$
$X = Cl$$-7$$67\%$$33\%$
$X = F$$3.2$$30\%$$70\%$

Which of the following statement$(s)$ is/are true concerning this series of $E_2$ reactions?

  • A
    Based on the $pK_a$ values of the conjugate acid,$I^{-}$ is the best leaving group and $F^{-}$ is the poorest leaving group.
  • B
    When $I^{-}$,$Br^{-}$,and $Cl^{-}$ are used as leaving groups,Zaitsev's rule is followed.
  • C
    $F^{-}$ is the strongest base (and therefore the poorest leaving group) and the transition state for reaction with fluoride as the leaving group has the least double bond character.
  • D
    $a$,$b$,and $c$ are true.

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Similar Questions

Consider the following reaction:
$CH_3-CH_2-CH(Br)-CH_3 \xrightarrow{alc. KOH, \Delta} CH_3-CH_2-CH=CH_2 (I) + CH_3-CH=CH-CH_3 (II)$
Which of the following statements are correct?
$a.$ $I$ is the major product of the reaction
$b.$ $II$ is the major product of the reaction
$c.$ Formation of $I$ is in accordance with Saytzeff's rule
$d.$ $II$ is more stable because it is more substituted

Decreasing the concentration of an electrophile (substrate) in a typical $S_N2$ reaction by a factor of $3$ will cause the reaction rate to

Which among the following is $NOT$ a feature of $S_N1$ mechanisms?

Among the following rules,the one which is applied in the given reaction is:
$CH_3-CH(Br)-CH_2-CH_3 \xrightarrow{Alc. KOH}$
$I. CH_3-CH=CH-CH_3$ (major product)
$II. CH_2=CH-CH_2-CH_3$ (minor product)

Match the following reactions with their mechanisms:
$(A)$ $CH_3CH_2CH_2I \xrightarrow{aq. KOH}$
$(B)$ $(CH_3)_3CCl \xrightarrow{H_2O}$
$(I)$ $S_N1$
$(II)$ $E_2$
$(III)$ $S_N2$
$(IV)$ $E_1$

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