The following data were obtained during the first order thermal decomposition of a gas $A$ at constant volume:
$A_{(g)} \rightarrow 2 B_{(g)} + C_{(g)}$

$S.No.$	$Time/s$	$Total Pressure/(atm)$
$1.$	$0$	$0.1$
$2.$	$115$	$0.28$

The rate constant of the reaction is . . . . . . $\times 10^{-2} \ s^{-1}$ (nearest integer).

The following is a first-order reaction:
$N_2O_5 \text{ (solution)} \rightarrow 2 NO_2 \text{ (solution)} + \frac{1}{2} O_2 \text{ (g)}$
In this reaction,$CCl_4$ is the solvent. The rate constant is $k = 5.0 \times 10^{-4} \ s^{-1}$. The initial concentration of $N_2O_5$ is $0.25 \ mol \ L^{-1}$.
$(i)$ What will be the initial rate of reaction?
$(ii)$ Calculate the half-life $(t_{1/2})$.
$(iii)$ How much time is required to complete $75\%$ of the reaction?
$(iv)$ Calculate the concentration of $N_2O_5$ and $NO_2$ after $30 \ min$.

Which of the following is a first order reaction?

For a first-order reaction,the rate constant is $4 \times 10^{-3} \, s^{-1}$. If the concentration of the reactant is $0.02 \, M$,what will be the rate of the reaction?

$N_2O_{(g)} \to N_{2(g)} + \frac{1}{2}O_{2(g)}$
In a closed vessel,the reaction follows first-order kinetics. If starting with pure $N_2O_{(g)}$,the total pressure after time $t$ is $P_t$ and after a very long time is $P_{\infty}$,then which of the following expressions is correct?

$A$ first order reaction is $75\%$ completed in $100 \ min$. How long will it take for its $87.5\%$ completion? (in $\min$)