The heat of combustion of carbon to $CO_2$ is $-393.5 \ kJ/mol$. The heat released upon formation of $35.2 \ g$ of $CO_2$ from carbon and oxygen gas is

  • A
    $+ 315 \ kJ$
  • B
    $- 630 \ kJ$
  • C
    $- 314.8 \ kJ$
  • D
    None of the above

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Which of the following equations corresponds to the definition of enthalpy of formation at $298 \ K$?

Calculate the heat of combustion (in $kJ$) of methane from the following data:
$(i)$ $C_{\text{(graphite)}} + 2H_{2(g)} \rightarrow CH_{4(g)} \quad \Delta H = -74.8 \ kJ$
(ii) $C_{\text{(graphite)}} + O_{2(g)} \rightarrow CO_{2(g)} \quad \Delta H = -393.5 \ kJ$
(iii) $H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)} \quad \Delta H = -286.2 \ kJ$

Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).

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For the reaction $C_{2}H_{6} \rightarrow C_{2}H_{4} + H_{2}$,the reaction enthalpy $\Delta_{r}H = \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \dots \, kJ \, mol^{-1}$. (Round off to the Nearest Integer). [Given: Bond enthalpies in $kJ \, mol^{-1} : C-C : 347, C=C : 611, C-H : 414, H-H : 436$]

For complete neutralization of $HCl$ with $NaOH,$ the heat of neutralization is ...... $kJ \ mol^{-1}$

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