The heat of reaction does not depend upon

  • A
    Temperature of the reaction
  • B
    Physical state of reactants and products
  • C
    Whether the reaction is carried out at constant pressure or at constant volume
  • D
    The method by which the final products are obtained from the reactants

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Using the data provided,calculate the bond energy $(kJ \ mol^{-1})$ of a $C \equiv C$ bond in $C_{2}H_{2}$. (Take the bond energy of a $C-H$ bond as $350 \ kJ \ mol^{-1}$)
$2C_{(s)} + H_{2(g)} \longrightarrow C_{2}H_{2(g)} \quad \Delta H = 225 \ kJ \ mol^{-1}$
$2C_{(s)} \longrightarrow 2C_{(g)} \quad \Delta H = 1410 \ kJ \ mol^{-1}$
$H_{2(g)} \longrightarrow 2H_{(g)} \quad \Delta H = 330 \ kJ \ mol^{-1}$

Fill in the blanks:
$(i)$ The enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states is called the ...... of that compound.
$(ii)$ The total heat change in a chemical reaction is equal to the algebraic sum of the heat changes of the individual steps of the reaction. This law was given by ............. .
$(iii)$ $A$ process during which there is no exchange of heat between the system and the surroundings is called an ................ process.
$(iv)$ The standard enthalpy value of any element in its standard state is considered to be ...... .

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$A$,$B$,$C$ and $D$ are some compounds. The enthalpy of formation of $A_{(g)}$,$B_{(g)}$,$C_{(g)}$ and $D_{(g)}$ is $9.7, -110, 81$ and $-393 \ kJ \ mol^{-1}$ respectively. What is $\Delta_r H$ (in $kJ \ mol^{-1}$) for the given reaction?
$A_{(g)} + 3B_{(g)} \longrightarrow C_{(g)} + 3D_{(g)}$

Given: $H_2 + 1/2 O_2 \rightarrow H_2O : \Delta H = -68.4 \ \text{kcal}$,$C + O_2 \rightarrow CO_2 : \Delta H = -94.0 \ \text{kcal}$,and $C_2H_5OH + 3O_2 \rightarrow 2CO_2 + 3H_2O : \Delta H = -327.0 \ \text{kcal}$. Calculate the heat of formation of $C_2H_5OH$ in $\text{kcal}$.

Consider the reaction $4NO_2(g) + O_2(g) \rightarrow 2N_2O_5(g)$, $\Delta_rH = -111 \ kJ$. If $N_2O_5(s)$ is formed instead of $N_2O_5(g)$, what will be the value of $\Delta_rH$ in $kJ$? (Given: $\Delta H_{sub} = 54 \ kJ \ mol^{-1}$ for $N_2O_5$)

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