The increasing order of boiling points of the following compounds is:

  • A
    $I < IV < II < III$
  • B
    $IV < I < II < III$
  • C
    $I < III < IV < II$
  • D
    $III < I < II < IV$

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An organic compound $C_6H_7N$ on reaction with $NaNO_2 / HCl$ at $273-278 \ K$ followed by warming with water gives $B$. $B$ reacts with concentrated $HNO_3$ to give $C$. What is $C$?

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$:
Assertion $A$: Aryl halides cannot be prepared by the replacement of the hydroxyl group of phenol by a halogen atom.
Reason $R$: Phenols react with halogen acids violently.
In the light of the above statements,choose the most appropriate from the options given below:

What is the name of the reaction between an aromatic acyl chloride and phenol in the presence of a base like $NaOH$ or pyridine?

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Explain the classification of phenols with examples.

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