The increasing order of nucleophilicity of the following nucleophiles is: $a. CH_3CO_2^-$,$b. H_2O$,$c. CH_3SO_3^-$,$d. OH^-$

The major product $A$ is:

The given reaction is $2$-methylbutanamide reacting with $KOBr$ and $\Delta$. What is the correct statement about the product?

The correct order of basicities of the following compounds is:
$1. CH_3-C(=NH)NH_2$ (Acetamidine)
$2. (CH_3)_2NH$ (Dimethylamine)
$3. CH_3-CH_2-NH_2$ (Ethylamine)
$4. CH_3-CONH_2$ (Acetamide)

Ethyl amine on heating with $CS_2$ in presence of $HgCl_2$ forms

Given below are two statements :
Statement $I$: Aniline reacts with conc. $H_2SO_4$ followed by heating at $453-473 \ K$ to give $p$-aminobenzene sulphonic acid (sulphanilic acid). This compound contains both nitrogen and sulphur,and thus it gives a blood red colour in the 'Lassaigne's test' due to the formation of ferric thiocyanate,$[Fe(SCN)]^{2+}$.
Statement $II$: In Friedel-Craft's alkylation and acylation reactions,aniline forms a salt with the $AlCl_3$ catalyst. Due to this,the nitrogen atom of aniline acquires a positive charge and acts as a deactivating group,preventing further reaction.
In the light of the above statements,choose the correct answer from the options given below :