The lowest value of heat of neutralization is obtained for

Which of the following reactions can be used to define the standard enthalpy of formation of $CO_{2_{(g)}}$?

One mole of ethanol $(l)$ was completely burnt in oxygen to form $CO_{2(g)}$ and $H_2O_{(l)}$. What is the $\Delta_r H^{\ominus}$ (in $kJ \ mol^{-1}$) for this reaction?
(The standard enthalpy of formation $(\Delta_f H^{\ominus})$ of $C_2H_5OH_{(l)}$,$CO_{2(g)}$ and $H_2O_{(l)}$ is respectively $-277, -393$ and $-286 \ kJ \ mol^{-1}$.)

The combustion enthalpies of carbon,hydrogen,and methane are $-395.5 \, kJ \, mol^{-1}$,$-285.8 \, kJ \, mol^{-1}$,and $-890.4 \, kJ \, mol^{-1}$ respectively at $25 \, ^oC$. The value of standard formation enthalpy of methane at that temperature is ..... $kJ \, mol^{-1}$.

Given:
$2C + 2O_2 \to 2CO_2 : \Delta H = -787 \text{ kJ}$
$H_2 + \frac{1}{2}O_2 \to H_2O : \Delta H = -286 \text{ kJ}$
$C_2H_2 + \frac{5}{2}O_2 \to 2CO_2 + H_2O : \Delta H = -1310 \text{ kJ}$
Calculate the heat of formation of acetylene $(C_2H_2)$ in $\text{kJ}$.

Calculate the enthalpy of formation of ethylene $(C_2H_4)$ from the following data:
$(I)$ $C_{\text{(graphite)}} + O_{2(g)} \longrightarrow CO_{2(g)}$; $\Delta H = -393.5 \ kJ$
$(II)$ $H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}$; $\Delta U = -256.2 \ kJ$
$(III)$ $C_2H_{4(g)} + 3 O_{2(g)} \longrightarrow 2 CO_{2(g)} + 2 H_2O_{(l)}$; $\Delta H = -1410.8 \ kJ$ (in $kJ$)