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If heterolytic and homolytic cleavage of a bond occurs,then which types of reactions occur?

What are the main types of organic reactions and their mechanisms?

Which of the following represent free radical substitution reaction $(FSR)$,electrophilic addition reaction $(EAR)$ and nucleophilic addition reaction $(NAR)$?
$I. CH_3-CH=CH_2 \xrightarrow{Cl_2/CCl_4} CH_3-CHCl-CH_2Cl$
$II. CH_3-CO-CH_3 \xrightarrow{HCN/OH^-} CH_3-C(OH)(CN)-CH_3$
$III. CH_3-CH_2-CH_3 \xrightarrow{Cl_2/h\nu} CH_3-CHCl-CH_3$

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Based on the provided energy profile diagram,transition state $2$ $(T.S. 2)$ is structurally most likely similar to which of the following?

To which of the following four types does this reaction belong: $B^{-} + R - A \to B - R + A^{-}$?

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