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The major products obtained from the reactions in List-$II$ are the reactants for the named reactions mentioned in List-$I$. Match List-$I$ with List-$II$ and choose the correct option.
List-$I$ List-$II$
$(P)$ Etard reaction $(1)$ Acetophenone $\xrightarrow{Zn-Hg, HCl}$
$(Q)$ Gattermann reaction $(2)$ Toluene $\xrightarrow[(ii) SOCl_2]{(i) KMnO_4, KOH}$
$(R)$ Gattermann-Koch reaction $(3)$ Benzene $\xrightarrow[\text{anhyd. } AlCl_3]{CH_3Cl}$
$(S)$ Rosenmund reduction $(4)$ Aniline $\xrightarrow[273-278 \ K]{NaNO_2 / HCl}$
$(5)$ Phenol $\xrightarrow[Zn, \Delta]{ }$

Ethanol on reaction with alkaline $KMnO_4$ gives $X$,which when reacted with methanol in the presence of an acid gives a sweet-smelling compound $Y$. $X$ and $Y$ respectively are:

The reaction sequence$(s)$ that would lead to $o$-xylene as the major product is (are)

$CH_3COOH \xrightarrow{LiAlH_4} A$
$A + CH_3COOH \xrightarrow{H_3O^+} B + H_2O$
In the above reactions,'$A$' and '$B$' respectively are:

Increasing order of boiling points in the following compounds is:
$I$. $CH_3COOH$
$II$. $CH_3CH_2CHO$
$III$. $CH_3CH_2CH_2OH$
$IV$. $CH_3COCH_3$

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