The number of coulombs required for the deposition of $107.870 \ g$ of silver is

  • A
    $96500$
  • B
    $48250$
  • C
    $193000$
  • D
    $10000$

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Electricity is passed through an acidic solution of $Cu^{2+}$ until all the $Cu^{2+}$ is exhausted, leading to the deposition of $300 \ mg$ of $Cu$ metal. Subsequently, a current of $600 \ mA$ is passed through the same solution for another $28 \ minutes$ while keeping the total volume of the solution fixed at $200 \ mL$. The total volume of oxygen evolved at $STP$ during the entire process is . . . . . . $mL$. (Nearest integer) [Given: $Cu^{2+}_{(aq)} + 2e^{-} \rightarrow Cu_{(s)}$, $E_{red}^0 = +0.34 \ V$; $O_{2(g)} + 4H^{+} + 4e^{-} \rightarrow 2H_2O$, $E_{red}^0 = +1.23 \ V$; Molar mass of $Cu = 63.54 \ g \ mol^{-1}$; Faraday Constant $= 96500 \ C \ mol^{-1}$; Molar volume at $STP = 22.4 \ L$]

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