The only cations present in a slightly acidic solution are $Fe^{3+}$,$Zn^{2+}$,and $Cu^{2+}$. The reagent that when added in excess to this solution would identify and separate $Fe^{3+}$ in one step is

$A$ solution is prepared by mixing a concentrated solution of $Co(NO_3)_2$ with a concentrated solution of $NaNO_2$ in $50\%$ acetic acid. $A$ solution of a salt containing metal $M$ is added to the mixture, and a yellow precipitate is formed. Metal $M$ is:

Which of the following statement$(s)$ is/are correct with reference to $Fe^{2+}$ and $Fe^{3+}$ ions?
$(1)$ $Fe^{3+}$ gives brown colour with potassium ferricyanide
$(2)$ $Fe^{2+}$ gives blue colour with potassium ferricyanide
$(3)$ $Fe^{3+}$ gives red colour with potassium thiocyanate
$(4)$ $Fe^{2+}$ gives brown colour with ammonium thiocyanate

An aqueous solution contains the ions as $Hg_2^{2+}$,$Hg^{2+}$,$Pb^{2+}$,and $Cd^{2+}$. The addition of dilute $HCl$ $(6 \ N)$ precipitates:

$H_2S$ gas is passed through an acidified solution containing $Ag^+$,$Cu^{2+}$,and $Zn^{2+}$ ions. Which of these will form a precipitate?

On treating a solid salt $A$ with dil. $H_2SO_4$ and warming,reddish-brown fumes of gas $B$ are evolved. Addition of $C$ to the salt solution of $A$ followed by freshly prepared starch solution and acidification with acetic acid produces a blue colour. $C$ may contain: