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(C) The reaction of alcohol with thionyl chloride $(SOCl_2)$ is the preferred method for preparing alkyl chlorides because the by-products formed ($SO

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$SOCl_2$

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(C) The reaction of alcohol with thionyl chloride $(SOCl_2)$ is the preferred method for preparing alkyl chlorides because the by-products formed ($SO_2$ and $HCl$) are gases. Since these by-products escape into the atmosphere,the resulting alkyl chloride is obtained in a pure state. The reaction is: $R-OH + SOCl_2 \rightarrow R-Cl + SO_2(g) + HCl(g)$.

The preferred reagent for the preparation of pure alkyl chloride from alcohol is

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