The rate constant for a first order reaction is $60 \ s^{-1}$. How much time will it take to reduce the initial concentration of the reactant to its $1/16^{th}$ value?

  • A
    $4.6 \times 10^{-2} \ s$
  • B
    $1.0 \times 10^{-2} \ s$
  • C
    $2.3 \times 10^{-2} \ s$
  • D
    $3.2 \times 10^{-2} \ s$

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The reaction $A_{(g)} \to 2B_{(g)} + C_{(g)}$ obeys the rate law,$r = K[A]$ where $K = 0.023 \ s^{-1}$. If $2.5 \ moles$ of $A$ were taken in a $5 \ L$ flask,how many moles of $A$ would remain left after $50 \ seconds$?

The following is a first-order reaction:
$N_2O_5 \text{ (solution)} \rightarrow 2 NO_2 \text{ (solution)} + \frac{1}{2} O_2 \text{ (g)}$
In this reaction,$CCl_4$ is the solvent. The rate constant is $k = 5.0 \times 10^{-4} \ s^{-1}$. The initial concentration of $N_2O_5$ is $0.25 \ mol \ L^{-1}$.
$(i)$ What will be the initial rate of reaction?
$(ii)$ Calculate the half-life $(t_{1/2})$.
$(iii)$ How much time is required to complete $75\%$ of the reaction?
$(iv)$ Calculate the concentration of $N_2O_5$ and $NO_2$ after $30 \ min$.

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Hydrolysis of sugar is a first order reaction. Write the reaction.

Time required for $90 \%$ completion of a first order reaction is '$x$' minute. Calculate the time required to complete $99.9 \%$ of the reaction at the same temperature.

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