The rate of dehydrohalogenation of which one among the following is the least?

  • A
    $CH_3-CH_2-CH_2-Br$
  • B
    $CH_3-CH_2-CH_2-Cl$
  • C
    $CH_3-CH_2-CH_2-I$
  • D
    $CH_3-CH(CH_3)-CH_2I$

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Arrange the following compounds in order of decreasing rate of hydrolysis for $SN_1$ reaction:
$(I)$ $C_6H_5CH_2Br$
$(II)$ $p-CH_3-C_6H_4-CH_2Br$
$(III)$ $p-(CH_3)_2CH-C_6H_4-CH_2Br$
$(IV)$ $p-CH_3CH_2-C_6H_4-CH_2Br$

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