The reaction of toluene with chlorine in the | vedclass

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Question

(D) The reaction of toluene with chlorine in the presence of a Lewis acid like ferric chloride $(FeCl_3)$ is an electrophilic aromatic substitution re

Vedclass · Accepted Answer

$o-$ and $p-$chlorotoluenes

Vedclass · Answer

(D) The reaction of toluene with chlorine in the presence of a Lewis acid like ferric chloride $(FeCl_3)$ is an electrophilic aromatic substitution reaction (chlorination). The methyl group $(-CH_3)$ attached to the benzene ring is an ortho/para-directing group due to its electron-donating inductive effect and hyperconjugation. Therefore,the chlorine electrophile $(Cl^+)$ attacks the ortho and para positions of the toluene ring,resulting in the formation of $o-$chlorotoluene and $p-$chlorotoluene as the major products. The reaction is: $C_6H_5CH_3 + Cl_2 \xrightarrow{FeCl_3} C_6H_4(CH_3)Cl + HCl$.

The reaction of toluene with chlorine in the presence of ferric chloride $(FeCl_3)$ gives predominantly:

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