The set containing only ambidentate ligands i | vedclass

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Question

(B) Ligands that possess two or more donor atoms but can coordinate through only one donor atom at a time are called ambidentate ligands.$NO_2^{\ominu

Vedclass · Accepted Answer

$NO_2^{\ominus}, CN^{\ominus}, SCN^{\ominus}$

Vedclass · Answer

(B) Ligands that possess two or more donor atoms but can coordinate through only one donor atom at a time are called ambidentate ligands.$NO_2^{\ominus}$ can coordinate through $N$ (nitro) or $O$ (nitrito).$CN^{\ominus}$ can coordinate through $C$ (cyano) or $N$ (isocyano).$SCN^{\ominus}$ can coordinate through $S$ (thiocyanato) or $N$ (isothiocyanato).Therefore,the set containing only ambidentate ligands is $NO_2^{\ominus}, CN^{\ominus}, SCN^{\ominus}$.

The set containing only ambidentate ligands in the following is:

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Assertion : When $NO$ reacts with $FeSO_4$,a brown coloured complex is formed.
Reason : In the complex,the coordination number of $Fe$ is $6$.

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