The standard Gibbs free energy change $\Delta G^{\circ}$ at $25^{\circ} C$ for the dissociation of $N_2O_{4(g)}$ to $NO_{2(g)}$ is (given, equilibrium constant $K_{eq} = 0.15, R = 8.314 \ J \ K^{-1} \ mol^{-1}$) (in $kJ$)

  • A
    $1.1$
  • B
    $4.7$
  • C
    $8.1$
  • D
    $38.2$

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Write the formula relating the equilibrium constant $K$ and $\Delta G^{\circ}$.

For the reversible reaction,$A_{(s)} + B_{(g)} \rightleftharpoons C_{(g)} + D_{(g)}$,$\Delta G^{\circ} = -350 \ kJ$,which one of the following statements is true?

The standard free energy change $(\Delta G^{\circ})$ for $50\%$ dissociation of $N_2O_4$ into $NO_2$ at $27^{\circ}C$ and $1\,atm$ pressure is $-x\,J\,mol^{-1}$. The value of $x$ is $......$ (Nearest Integer)
[Given: $R = 8.31\,J\,K^{-1}\,mol^{-1}$,$\log 1.33 = 0.1239$,$\ln 10 = 2.3$]

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At $300 \ K$,ozone is $50\%$ dissociated. The standard free energy change at this temperature and $1 \ atm$ pressure is $(-) \dots \ J \ mol^{-1}$ (Nearest integer).
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