The values of $K_{sp}$ of two sparingly soluble salts $Ni(OH)_2$ and $AgCN$ are $2.0 \times 10^{-15}$ and $6 \times 10^{-17}$ respectively. Which salt is more soluble? Explain.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) For $AgCN$: $AgCN \rightleftharpoons Ag^{+} + CN^{-}$. Let solubility be $S_1$. $K_{sp} = S_1^2 = 6 \times 10^{-17}$. Thus,$S_1 = \sqrt{6 \times 10^{-17}} \approx 7.75 \times 10^{-9} \ M$.
For $Ni(OH)_2$: $Ni(OH)_2 \rightleftharpoons Ni^{2+} + 2OH^{-}$. Let solubility be $S_2$. $K_{sp} = (S_2)(2S_2)^2 = 4S_2^3 = 2.0 \times 10^{-15}$.
$S_2^3 = 0.5 \times 10^{-15} = 5 \times 10^{-16}$.
$S_2 = \sqrt[3]{5 \times 10^{-16}} \approx 7.94 \times 10^{-6} \ M$.
Comparing $S_1$ and $S_2$,$S_2 > S_1$,therefore $Ni(OH)_2$ is more soluble.

Explore More

Similar Questions

If the solubility product of $BaSO_4$ is $1.44 \times 10^{-12}$,then the solubility of $SO_4^{2-}$ is .....

If the solubility product of $HgSO_4$ is $6.4 \times 10^{-5}$,then its solubility is:

Solid $Ba(NO_3)_2$ is gradually dissolved in $1 \times 10^{-4} \ M \ Na_2CO_3$ solution. At what concentration of $Ba^{+2}$ will the precipitation of $BaCO_3$ start? (Given: $K_{sp}$ of $BaCO_3 = 5.1 \times 10^{-9}$)

Solubility of calcium phosphate (molecular mass,$M$) in water is $W \ g$ per $100 \ mL$ at $25^{\circ} C$. Its solubility product at $25^{\circ} C$ will be approximately.

The solubility product of the sparingly soluble salt $AB_2$ is $2.56 \times 10^{-10}$ at $298 \ K$. Calculate its solubility in $mol \ dm^{-3}$ at the same temperature?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo