The wavelength of the first line of the Balmer series is $656 \ nm$. Calculate the wavelength of the second line of this series. (Note: First line means $n=3 \to n=2$ and second line means $n=4 \to n=2$)

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The Rydberg formula for the Balmer series is given by: $\frac{1}{\lambda} = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)$,where $n_1 = 2$.
For the first line $(n_2 = 3)$: $\frac{1}{656} = R_H \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R_H \left( \frac{1}{4} - \frac{1}{9} \right) = R_H \left( \frac{5}{36} \right)$.
For the second line $(n_2 = 4)$: $\frac{1}{\lambda_2} = R_H \left( \frac{1}{2^2} - \frac{1}{4^2} \right) = R_H \left( \frac{1}{4} - \frac{1}{16} \right) = R_H \left( \frac{3}{16} \right)$.
Dividing the two equations: $\frac{\lambda_2}{656} = \frac{5/36}{3/16} = \frac{5}{36} \times \frac{16}{3} = \frac{80}{108} = \frac{20}{27}$.
Therefore,$\lambda_2 = 656 \times \frac{20}{27} \approx 486 \ nm$.

Explore More

Similar Questions

If the shortest wavelength of the Lyman series of the $H$ atom is $x$,then calculate the total energy of the $H$ atom in the first excited state.

State whether the following statements are true or false:
$(i)$ When an electron in a hydrogen atom returns from the third excited state to the ground state,it emits frequencies corresponding to lines in the Lyman,Balmer,and Paschen series.
$(ii)$ When an electron in a hydrogen atom returns from the third excited state to the ground state,it emits radiation with wavelengths corresponding to the Pfund series,which has very high frequencies.

In the spectrum of $Li^{2+}$,the difference between two energy levels is $2$ and their sum is $4$. Find the wavelength of the photon emitted during the transition between these two energy states.

If the velocity of the revolving electron of $He^{+}$ in the first orbit $(n=1)$ is $v$,what is the velocity of the electron in the second orbit $(n=2)$?

In the hydrogen spectrum,if $n = 4$,what is the ratio of the number of lines in the emission spectrum in the ultraviolet and visible regions?

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo