Three thermochemical equations are given below:
$(i) C_{(graphite)} + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = x \ kJ \ mol^{-1}$
$(ii) C_{(graphite)} + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\circ = y \ kJ \ mol^{-1}$
$(iii) CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\circ = z \ kJ \ mol^{-1}$
Based on the above equations,find out which of the relationship given below is correct.

  • A
    $z = x + y$
  • B
    $x = y + z$
  • C
    $y = 2z - x$
  • D
    $x = y - z$

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The heats of hydrogenation for $3-$-methylbutene and $2-$-pentene are $-30\, kcal/mol$ and $-28\, kcal/mol$ respectively. The heats of combustion of $2-$-methylbutane and pentane are $-784\, kcal/mol$ and $-782\, kcal/mol$ respectively. All the values are given under standard conditions. Taking into account that combustion of both alkanes gives the same products,what is $\Delta H$ (in $kcal/mol$) for the following reaction under same conditions?
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