Toluene in the vapour phase is in equilibrium with a solution of benzene and toluene having mole fraction of toluene $0.50$. If vapour pressure of pure benzene is $119 \ torr$ and that of toluene is $37.0 \ torr$ at the same temperature,mole fraction of toluene in vapour phase will be:

  • A
    $0.462$
  • B
    $0.237$
  • C
    $0.506$
  • D
    $0.325$

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$X$ is a non-volatile solute and $Y$ is a volatile solvent. The following vapour pressures are observed by dissolving $X$ in $Y$ at different concentrations:
| $X / \text{mol L}^{-1}$ | $Y / \text{mm of Hg}$ |
| :--- | :--- |
| $0.10$ | $p_1$ |
| $0.25$ | $p_2$ |
| $0.01$ | $p_3$ |
The correct order of vapour pressures is:

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