Under the same reaction conditions,initial concentration of $1.386 \ mol \ dm^{-3}$ of a substance becomes half in $40 \ s$ and $20 \ s$ through first order and zero order kinetics,respectively. The ratio $\left(\frac{k_1}{k_0}\right)$ of the rate constants for first order $\left(k_1\right)$ and zero order $\left(k_0\right)$ of the reactions is:

  • A
    $0.5 \ mol^{-1} \ dm^3$
  • B
    $1.0 \ mol \ dm^{-3}$
  • C
    $1.5 \ mol \ dm^{-3}$
  • D
    $2.0 \ mol^{-1} \ dm^3$

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Similar Questions

For the following reaction
$2X + Y \xrightarrow{i} P$
the rate of reaction is $\frac{d[P]}{dt} = k[X]$. Two moles of $X$ are mixed with one mole of $Y$ to make $1.0 \ L$ of solution. At $50 \ s$,$0.5 \ mole$ of $Y$ is left in the reaction mixture. The correct statement$(s)$ about the reaction is(are)
(Use: $\ln 2 = 0.693$)
$(A)$ The rate constant,$k$,of the reaction is $13.86 \times 10^{-4} \ s^{-1}$.
$(B)$ Half-life of $X$ is $50 \ s$.
$(C)$ At $50 \ s$,$-\frac{d[X]}{dt} = 13.86 \times 10^{-3} \ mol \ L^{-1} \ s^{-1}$.
$(D)$ At $100 \ s$,$-\frac{d[Y]}{dt} = 3.46 \times 10^{-3} \ mol \ L^{-1} \ s^{-1}$.

Which of the following reaction mechanisms will have a fractional order with respect to $A_2$ or $B_2$?

At $100\,^\circ C,$ the gaseous reaction $A_{(g)} \rightarrow 2B_{(g)} + C_{(g)}$ is found to be first order. Starting with pure $A,$ if at the end of $10\,\min$,the total pressure of the system is $160\,mm$ and after a long time,when dissociation of $A$ was complete,it was $300\,mm.$ The partial pressure of $A$ at the end of $10\,\min$ is .......... $mm$

$t_{100\%}$ is the time required for the $100\%$ completion of the reaction, while $t_{1/2}$ is the time required for $50\%$ of the reaction to be completed. Which of the following options correctly represents the relation between $t_{100\%}$ and $t_{1/2}$ for zero and first-order reactions, respectively?

The given graph is a representation of kinetics of a reaction. The $y$ and $x$ axes for zero and first order reactions,respectively are

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