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Which among the following compounds is the most acidic?

What is $A$ in the following reaction?

In the presence of a small amount of phosphorus,aliphatic carboxylic acids react with chlorine or bromine to yield a compound in which $\alpha$-hydrogen has been replaced by a halogen. This reaction is known as:

Ethyl acetate $\xrightarrow[{(2)\,HOH}]{{(1)\,C{H_3}MgBr\,\left[ {Excess} \right]}}P$
The product $P$ will be

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Which of the following is used in perfumery?

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